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Equilibrium sorption of the Thermally Treated Rice Husk (TTRH) for Sulfamethazine (SMT) adsorption was studied. The Physico-chemical properties of the modified rice husk were determined. The equilibrium sorption data were fitted into Langmuir, Freundlich and Dubinin–Radushkevich isotherms. Of the three adsorption isotherm, the R2 value of Langmuir isotherm model was the highest. Also compared to other isotherms the AARE coefficient for the Langmuir isotherm is low, which indicates favorable sorption. The maximum monolayer coverage (qm) from Langmuir isotherm model was determined to be 19.11 mg/g, the separation factor indicating a favorable sorption experiment is 0.446. Also from Freundlich Isotherm model, the sorption intensity (n) which indicates favorable sorption and the correlation value are 1.84 and 3.79 respectively. The mean free energy was estimated from Dubinin–Radushkevich isotherm model to be 9.18 KJ/mol which clearly proved that the adsorption experiment followed a physical process.
Peng X, Hu F, Dai H, Xiong Q. Study of the adsorption mechanism of ciprofloxacin antibiotics onto graphitic ordered mesoporous carbons. Journal of the Taiwan Institute of Chemical Engineers. 2016;8:1–10.
Balarak D, Kord Mostafapour F. Adsorption of acid red 66 dye from aqueous solution by heat-treated rice husk. Research Journal of Chemistry and Environment. 2018;22(12):80-84.
Amini M, Khanavi M, Shafiee A. simple high-performance liquid chromatographic method for determination of ciprofloxacin in human plasma. Iranian Journal of Pharmaceutical Research. 2004;2:99-101.
Carabineiro A, Thavorn-Amornsri T, Pereira F, Figueiredo L. Adsorption of ciprofloxacin on surface modified carbon materials. Water Res. 2011;45: 4583-91.
Ibezim EC, Ofoefule SI, Ejeahalaka N, Orisakwe E. In vitro adsorption of ciprofloxacin on activated charcoal and Talc. Am J Ther. 1999;6(4):199-201.
Ghauch A, Tuqan A, Assi HA. Elimination of amoxicillin and ampicillin by micro scale and nano scale iron particles. Environ Pollut. 2009;157:1626–1635.
Balarak D, Azarpira H, Mostafapour FK. Adsorption isotherm studies of tetracycline antibiotics from aqueous solutions by maize stalks as a cheap biosorbent. International Journal of Pharmacy & Technology. 2016;8(3):16664-75.
Chen WR, Huang CH. Adsorption and transformation of tetracycline antibiotics with aluminum oxide. Chemosphere. 2010; 79:779–785.
Ahmadi S, Banach A, Kord Mostafapour F. Study survey of cupric oxide nanoparticles in removal efficiency of ciprofloxacin antibiotic from aqueous solution: Adsorption isotherm study. Desalination and Water Treatment. 2017;89:297-303.
Balarak D, Mostafapour FK. Photocatalytic degradation of amoxicillin using UV/Synthesized NiO from pharmaceutical wastewater. Indonesian Journal of Chemistry. 2019;19(1):211-218.
Alexy R, Kumpel T, Kummerer K. Assessment of degradation of 18 antibiotics in the closed bottle test. Chemosphere. 2004;57:505–512.
Balarak D, Mostafapour F, Bazrafshan E, Saleh TA. Studies on the adsorption of amoxicillin on multi-wall carbon nanotubes. Water Science and Technology. 2017; 75(7):1599-1606.
Danalıoğlu ST, Bayazit ŞS, Kerkez Kuyumcu Ö, Salam MA. Efficient removal of antibiotics by a novel magnetic adsorbent: Magnetic activated carbon/ chitosan (MACC) nanocomposite. J Mol Liq. 2017;240:589–596.
Aksu Z, Tunc O. Application of biosorption for Penicillin G removal: Comparison with activated carbon. Process Biochemistry. 2005;40(2):831-47.
Ji L, ChenW, Duan L and Zhu D. Mechanisms for strong adsorption of tetracycline to carbon nanotubes: A comparative study using activated carbon and graphite as adsorbents. Environ. Sci. Technol. 2009,43(7):2322–27.
Choi KJ, Kim SG, Kim SH. Removal of antibiotics by coagulation and granular activated carbon filtration. J. Hazard. Mater. 2008;151:38–43.
Zhang W, He G, Gao P, Chen G. Development and characterization of composite nanofiltration membranes and their application in concentration of antibiotics. Sep Purif Technol. 2003;30:27–35.
Balarak D, Azarpira H. Rice husk as a Biosorbent for Antibiotic Metronidazole Removal: Isotherm Studies and Model validation. International Journal of ChemTech Research. 2016;9(7):566-573.
Yu F, Li Y, Han S, Jie Ma J. Adsorptive removal of antibiotics from aqueous solution using carbon Materials. Chemosphere. 2016;153;365–385.
Zhang L, Song X, Liu X, Yang L, Pan F. Studies on the removal of tetracycline by multi-walled carbon nanotubes, Chem. Eng. J. 2011;178:26–33.
Yalçın N, Sevinç V. Studies of the surface area and porosity of activated carbons prepared from rice husks. Carbon. 2000; 38(14):1943–1945.
Guo Y, Yu K, Wang, Z, Hongding Xu H. Effects of activation conditions on preparation of porous carbon from rice husk. Carbon. 2003;41(8):1645–1648.
Li M, Shu D, Jiang L. Cu (II)-influenced adsorption of ciprofloxacin from aqueous solutions by magnetic graphene oxide/ nitrilotriacetic acid nanocomposite: Competition and enhancement mechanisms. Chem Eng J. 2017;319:219–228.
Liu H, Liu W, Zhang J, Zhang C, Ren L, Li Y. Removal of cephalexin from aqueous solution by original and Cu(II)/Fe(III) impregnated activated carbons developed from lotus stalks kinetics and equilibrium studies. J Hazard Mater. 2011;185:1528–35.
Putra EK, Pranowoa R, Sunarsob J, Indraswatia N, Ismadjia S. Performance of activated carbon and bentonite for adsorption of amoxicillin from wastewater: mechanisms, isotherms and kinetics. Water Res. 2009;43:2419-2430.
Balarak D, Azarpira H. Biosorption of Acid Orang 7 using dried Cyperus Rotundus: Isotherm Studies and Error Functions. International Journal of Chem Tech Research. 2016;9(9):543-9.
Liu W, Zhang J, Zhang C, Ren L. Sorption of norfloxacin by lotus stalk-based activated carbon and iron-doped activated alumina: mechanisms, isotherms and kinetics. Chem Eng J. 2011;171(2):431–438.
Hu D, Wang L. Adsorption of amoxicillin onto quaternized cellulose from flax noil: Kinetic, equilibrium and thermodynamic study, J. Taiwan Inst. Chem Eng. 2016;64: 227-234.
Wang F, Yang B, Wang H, Song Q, Tan F, Cao Y. Removal of ciprofloxacin from aqueous solution by a magnetic chitosan grafted graphene oxide composite. J Mol Liq. 2016;222:188–194.
Shokohi R, Jafari SJ, Saidi S, Ghamar N, Siboni M. Removal dye Acid Blue 113(AB113) dye from aqueous environment by adsorption on Activated Redmud. Kordestan Univ Med Sci J. 2011; 16(2):55-65.
Peterson JW, Petrasky LJ, Seymourc MD, Burkharta RS, Schuilinga AB. Adsorption and breakdown of penicillin antibiotic in the presence of titanium oxide nanoparticles in water. Chemosphere. 2012;87(8):911–7.
Kyzas GZ, Bikiaris DN, Seredych M, Bandosz TJ, Deliyanni EA. Removal of dorzolamide from biomedical wastewaters with adsorption onto graphite oxide/poly(acrylic acid) grafted chitosan nanocomposite. Bioresour Technol. 2014; 152:399–406.
Balarak D, Mostafapour FK, Joghataei A. Adsorption of Acid Blue 225 dye by Multi Walled Carbon Nanotubes: Determination of equilibrium and kinetics parameters. Der Pharma Chemica. 2016;8(8):138-45.
Balarak D. Kinetics, Isotherm and Thermodynamics Studies on Bisphenol A Adsorption using Barley husk. International Journal of ChemTech Research. 2016; 9(5):681-90.
Adrianoa WS, Veredasb V, Santanab CC, Gonçalves LRB. Adsorption of amoxicillin on chitosan beads: Kinetics, equilibrium and validation of finite bath models. Biochemical Engineering Journal. 2005; 27(2):132-37.
Gao J, Pedersen JA. Adsorption of sulfonamide antimicrobial agents to clay minerals. Environ. Sci. Technol. 2005; 39(24):9509-16.
Diyanati RA, Yousefi Z, Cherati JY, Balarak D. Investigating phenol absorption from aqueous solution by dried azolla. Journal of Mazandaran University of Medical Science. 2013;22(2):13-21.
Diyanati RA, Yousefi Z, Cherati JY, Balarak D. The ability of Azolla and lemna minor biomass for adsorption of phenol from aqueous solutions. Journal of Mazandaran University Medical Science. 2013;23(106):17-23.
Azarpira H, Mahdavi Y, Khaleghi O. Thermodynamic Studies on the Removal of Metronidazole Antibiotic by Multi-Walled Carbon Nanotubes. Der Pharmacia Lettre. 2016;8(11):107-13.
Mahvi AH, Mostafapour FK, Balarak D. Biosorption of tetracycline from aqueous solution by azolla filiculoides: Equilibrium kinetic and thermodynamics studies. Fresenius Environmental Bulletin. 2018; 27(8):5759-5767.