Survey Electrocoagulation Process in Removal of Norfloxacin Antibiotic from Aqueous Solutions

Main Article Content

Davoud Balarak
Mahdethe Dashtizadeh
Raphael Shadai Oguike
Kethineni Chandrika

Abstract

Pharmaceutical compounds have been recognized as a hazardous class of organic pollutants due to their long term effects towards the aquatic environment. The present work studies the efficiency of electrogalation (EC) process in removal Norfloxacin (NFX) from aqueous solutions by aluminum electrodes. This study experimentally was run in a batch electrochemical reactor (1.5 L glass beaker) and six electrodes which installed in parallel. In each of test, 1 L of wastewater added to the test reactor, then effect of four parameters including the voltage 10-60 V (current density: 1,2,3 and 4 mA/cm2), reaction time (5-60 min) initial concentration of NFX and the pH of wastewater (pH=3-9) on process performance were investigated. Results of this study showed that the efficiency of the system could be promoted by increasing the contact time, initial pH of the solution, and the applied voltage. However, the efficiency of EC process has decreased, when higher level of NFX ions was presented in the aqueous phase. The optimal conditions for Norfloxacin removal were: pH 7, initial NFX concentration 25 mg/L, voltage 60 V and reaction time 45 min and the highest removal rate was under these conditions 98.4%. The results of this study indicate that EC process could be applied for the removal of NFX from aqueous solution with a high efficiency.

Keywords:
Electrocoagulation, norfloxacin, energy consumption.

Article Details

How to Cite
Balarak, D., Dashtizadeh, M., Oguike, R. S., & Chandrika, K. (2020). Survey Electrocoagulation Process in Removal of Norfloxacin Antibiotic from Aqueous Solutions. Journal of Pharmaceutical Research International, 32(3), 53-60. https://doi.org/10.9734/jpri/2020/v32i330413
Section
Original Research Article

References

Balarak D, Mahdavi Y, Kord Mostafapour F, Joghataei A. Batch removal of acid blue 292 dye by biosorption onto lemna minor: Equilibrium and kinetic studies. J Hum Environ Health Promot. 2016;2(1):9-19.

Balarak D, Dashtizadeh M, Zafariyan M, Sadeghi M. Equilibrium, isotherm and kinetic adsorption studies of direct blue 71 onto raw kaolin. J Hum Environ Health Promot. 2018;4(4):153-158.

Tazerodi AJ, Akbari H, Mostafapour F. Adsorption of catechol FROM aqueous solutions using graphene oxide. J. Hum. Environ. Health Promot. 2018;4(4):175-179.

Balarak D, Dashtizadeh M, Abasizade H, Baniasadi M. Isotherm and kinetic evaluation of acid blue 80 dye adsorption on surfactant-modified bentonite. J Hum Environ Health Promot. 2018;4(2):75-80.

Garoma T, Umamaheshwar SH, Mumper A. Removal of sulfadiazine, sulfamethizole, sulfamethoxazole, and sulfathiazole from aqueous solution by ozonation. Che-mosphere. 2010;79;814–20.

Gulkowsk A, Leung HW, So MK, Taniyasu S, Yamashita N. Removal of antibiotics from wastewater by sewage treatment facilities in Hong Kong and Shenzhen, China. Water Res. 2008;42:395-403.

Balarak D, Mostafapour FK, Azarpira H. Adsorption isotherm studies of tetracycline antibiotics from aqueous solutions by maize stalks as a cheap biosorbent. Inter J Pharm Tech. 2016;8(3);16664-675.

Rostamian R, Behnejad H. A comparative adsorption study of sulfamethoxazole onto graphene and graphene oxide nanosheets through equilibrium, kinetic and thermodynamic modeling. Process Safety and Environmental Protection. 2016;102: 20-29.

Choi KJ, Kim SG, Kim SH. Removal of antibiotics by coagulation and granular activated carbon filtration. J Hazard Mater. 2008; 151:38–43.

Aksu Z, Tunc O. Application of biosorption for Penicillin G removal: Comparison with activated carbon. Process Biochemistry. 2005;40(2):831-47.

Peng X, Hu F, Dai H, Xiong Q. Study of the adsorption mechanism of ciprofloxacin antibiotics onto graphitic ordered mesoporous carbons. Journal of the Taiwan Institute of Chemical Engineers. 2016;8:1–10.

Alexy R, Kumpel T, Kummerer K. Assessment of degradation of 18 antibiotics in the closed bottle test. Chemosphere. 2004;57:505–512.

Maria HL, Ribeiro E, Isabel AC. Modelling the adsorption kinetics of erythromycin onto neutral and anionic resins. Bioprocess Biosyst Eng. 2003;26:49–55.

Yu F, Li Y, Han S, Ma J. Adsorptive removal of antibiotics from aqueous solution using carbon materials. Chemosphere. 2016;153:365–385.

Assadi A, Soudavari A, Mohammadian M. Comparison of electrocoagulation and chemical coagulation processes in removing reactive red 196 from aqueous solution. J Hum Environ Health Promot. 2016;1(3):172-82.

Chafi M, Gourich B, Essadki AH, Vial C, Fabregat A. Comparison of electro-coagulation using iron and aluminum electrodes with chemical coagulation for the removal of a highly soluble acid dye. Desalination. 2011;281:285- 292.

Kamaraj R, Vasudevan S, Evaluation of electrocoagulation process for the removal of strontium and cesium from aqueous solution. Chem Engine Res Des. 2015;93: 522-530.

Sengil IA, Ozacar M. The decolonization of C.I. Reactive Black 5 in aqueous solution by Electrocoagulation using sacrificial iron electrodes. J Hazard Mater. 2009;161 (2-3):1369–76.

Khandegar V, Saroha AK. Electro-coagulation for the treatment of textile industry Effluent–A review, J Environ manage. 2013;128:949-963.

Barışçı S, Turkay O. Optimization and modeling using the Response Surface Methodology (RSM) for ciprofloxacin removal by electrocoagulation. Water Sci Techno. 2016;73:1673-1679.

Parsa JB, Panah TM, Chianeh FN. Removal of ciprofloxacin from aqueous solution by continuous flow electro-coagulation process. Korean J Chem Eng. 2016;33:893-901.

Daneshvar N, Khataee AR, Amani AR, Rasoulifard MH. Decolonization of C.I. acid yellow 23 solution by electrocoagulation process: Investigation of operational parameters and evaluation of Specific Electrical Energy Consumption (SEEC). J Hazard Mater. 2007;148(3):566-72.

Can OT, Bayramoglu M, and Kobya M. Decolonization of reactive dye solutions by electro-coagulation using aluminum electrodes. Ind Eng Chem Res. 2003; 42(14):3391-6.

Basiri Parsa J, Rezaei Vahidian H, Soleymani AR, Abbasi M. Removal of Acid Brown 14 in aqueous media by electrocoagulation: Optimization para-meters and minimizing of energy consumption. Desalination. 2011;278(1-3): 295–302.

Nezamaldin D, Hossien AS, Tizpar A, Decolorization of orange II by electrocoagulation Method, Separation and Purification Technology. 2003;31(2):153-162.

Nadi H, Alizadeh M, Ahmadabadi M, Yari AR, Hashemi S. Removal of reactive dyes green, orange and yellow) from aqueous solutions by peanut shell powder as a natural adsorbent. Arch Hyg Sci. 2012;1 (2):41-7.

Abdelwahaba O, Aminb NK, El-Ashtoukhy Z. Electrochemical removal of phenol from oil refinery wastewater. J Hazard Mater. 2009;163 (2-3):711-716.

Zazouli MA, Taghavi M, Bazrafshan E. Influences of solution chemistry on phenol removal from aqueous environments by electrocoagulation process using aluminum electrodes. Journal of Health Scope. 2012;1(2):65-70.

Ghalwa NMA, Saqer AM, Format NB. Removal of reactive Red 24 dye by clean electrocoagulation process using iron and Aluminum electrodes. Journal of Chemical Engineering & Process Technology. 2016; 18:195-204.

Kuleyin A, Balcıoglu EB. Investigation of the removal of crystal violet by electrocoagulation method. Fresen Environ Bull. 2009;18(9):1597-1602.

Balarak D, Chandrika K and Attaolahi M. Assessment of effective operational parameters on removal of amoxicillin from synthetic wastewater using electro-coagulation process. Journal of Pharmaceutical Research International. 2019;29(1):1-8.

Balarak D, Ganji F, Choi S, Lee SM, Shim MJ. Effects of operational parameters on the removal of acid blue 25 dye from aqueous solutions by electrocoagulation. Applied Chemistry for Engineering. 2019; 30(6):742-748.